It sounds like your diet is OK. All the supplements you buy should tell you when to take them on the package. I know the NO is a pre-workout and if your taking three shakes a day, they could be when you wake up, Post workout and before bed.
As for your workout as a beginner you should start with the basics squats, bench press, Dead lifts, Shoulder presses. For a beginner I would workout three days a week doing basic exercises. If you want to work your arms to you can do Barbell curls and triceps extensions.
Once you have worked out for six months or so you can add more exercises.
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